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The factors help to estimate emissions from various sources of air pollution. In most cases, the factors are simply averages of all available data of acceptable quality, and are generally assumed to be representative of long-term averages. The equation for the estimation of emissions before emission reduction controls are applied is: E = A × EF
A great many computer programs for calculating the dispersion of air pollutant emissions were developed during that period of time and they were called "air dispersion models". The basis for most of those models was the Complete Equation For Gaussian Dispersion Modeling Of Continuous, Buoyant Air Pollution Plumes shown below: [4] [5]
An emission intensity (also carbon intensity or C.I.) is the emission rate of a given pollutant relative to the intensity of a specific activity, or an industrial production process; for example grams of carbon dioxide released per megajoule of energy produced, or the ratio of greenhouse gas emissions produced to gross domestic product (GDP).
An emission spectrum is formed when an excited gas is viewed directly through a spectroscope. Schematic diagram of spontaneous emission. Emission spectroscopy is a spectroscopic technique which examines the wavelengths of photons emitted by atoms or molecules during their transition from an excited state to a lower energy state.
The first general metric for green chemistry remains one of the most flexible and popular ones. Roger A. Sheldon’s environmental factor (E-factor) can be made as complex and thorough or as simple as desired and useful. [10] The E-factor of a process is the ratio of the mass of waste per mass of product:
In 1916, Albert Einstein proposed that there are three processes occurring in the formation of an atomic spectral line. The three processes are referred to as spontaneous emission, stimulated emission, and absorption. With each is associated an Einstein coefficient, which is a measure of the probability of that particular process occurring.
The rate of spontaneous emission (i.e., the radiative rate) can be described by Fermi's golden rule. [17] The rate of emission depends on two factors: an 'atomic part', which describes the internal structure of the light source and a 'field part', which describes the density of electromagnetic modes of the environment.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".