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For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
The name cam clay asserts that the plastic volume change typical of clay soil behaviour is due to mechanical stability of an aggregate of small, rough, frictional, interlocking hard particles. [3] The Original Cam-Clay model is based on the assumption that the soil is isotropic, elasto-plastic, deforms as a continuum, and it is not affected by ...
The Universal Soil Loss Equation (USLE) is a widely used mathematical model that describes soil erosion processes. [1]Erosion models play critical roles in soil and water resource conservation and nonpoint source pollution assessments, including: sediment load assessment and inventory, conservation planning and design for sediment control, and for the advancement of scientific understanding.
Some erosion models are purely statistical, others more mechanistic (or physically based). Two of the more widely used soil erosion models in North America are the Revised Universal Soil Loss Equation (RUSLE) and the Water Erosion Prediction Project erosion model (WEPP). Much of the mineland erosion literature is solely focused on fitting or ...
Scale models offer a useful approximation of physical or chemical processes at a size that allows for greater ease of visualization. [1] The model may be created in one (core, column), two (plan, profile), or three dimensions, and can be designed to represent a variety of specific initial and boundary conditions as needed to answer a question.
SWAT (soil and water assessment tool) is a river basin scale model developed to quantify the impact of land management practices in large, complex watersheds. SWAT is a public domain software enabled model actively supported by the USDA Agricultural Research Service at the Blackland Research & Extension Center in Temple, Texas , USA. [ 1 ]
The coupling constant, indicating a small frequency difference between split signal peaks, would be smaller than in an undecoupled spectrum. [ 1 ] Looking at a compound's off-resonance proton-decoupled 13 C spectrum can show how many hydrogens are bonded to the carbon atoms to further help elucidate the chemical structure .