Search results
Results From The WOW.Com Content Network
Tafel plot for an anodic process . The Tafel equation is an equation in electrochemical kinetics relating the rate of an electrochemical reaction to the overpotential. [1] The Tafel equation was first deduced experimentally and was later shown to have a theoretical justification. The equation is named after Swiss chemist Julius Tafel.
Such rates provide insights into the structure and bonding in the analyte and the electrode. For example, the exchange current densities for platinum and mercury electrodes for reduction of protons differ by a factor of 10 10, indicative of the excellent catalytic properties of platinum. Owing to this difference, mercury is the preferred ...
In February 1976, work commenced to automate the methods contained in the USAF Stability and Control DATCOM, specifically those contained in sections 4, 5, 6 and 7.The work was performed by the McDonnell Douglas Corporation under contract with the United States Air Force in conjunction with engineers at the Air Force Flight Dynamics Laboratory in Wright-Patterson Air Force Base.
The upper graph shows the current density as function of the overpotential η . The anodic and cathodic current densities are shown as j a and j c, respectively for α=α a =α c =0.5 and j 0 =1mAcm −2 (close to values for platinum and palladium).
the slope field is an array of slope marks in the phase space (in any number of dimensions depending on the number of relevant variables; for example, two in the case of a first-order linear ODE, as seen to the right). Each slope mark is centered at a point (,,, …,) and is parallel to the vector
Specifically, a straight line on a log–log plot containing points (x 0, F 0) and (x 1, F 1) will have the function: = (/) (/), Of course, the inverse is true too: any function of the form = will have a straight line as its log–log graph representation, where the slope of the line is m.
The software developed by Deb can be downloaded, [7] which implements the NSGA-II procedure with GAs, or the program posted on Internet, [8] which implements the NSGA-II procedure with ES. Just a general form of the equation, a plot of the objective function, boundaries of the object variables and the coordinates of global minima are given herein.
Van 't Hoff plot in mechanism study. A chemical reaction may undergo different reaction mechanisms at different temperatures. [13] In this case, a Van 't Hoff plot with two or more linear fits may be exploited. Each linear fit has a different slope and intercept, which indicates different changes in enthalpy and entropy for each distinct ...