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The helium dimer is a van der Waals molecule with formula He 2 consisting of two helium atoms. [2] This chemical is the largest diatomic molecule—a molecule consisting of two atoms bonded together. The bond that holds this dimer together is so weak that it will break if the molecule rotates, or vibrates too much.
Helium is the least water-soluble monatomic gas, [96] and one of the least water-soluble of any gas (CF 4, SF 6, and C 4 F 8 have lower mole fraction solubilities: 0.3802, 0.4394, and 0.2372 x 2 /10 −5, respectively, versus helium's 0.70797 x 2 /10 −5), [97] and helium's index of refraction is closer to unity than that of any other gas. [98]
A space-filling model of the diatomic molecule dinitrogen, N 2. Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen (H 2) or oxygen (O 2), then it is said to be homonuclear.
Helium is the smallest and the lightest noble gas and one of the most unreactive elements, so it was commonly considered that helium compounds cannot exist at all, or at least under normal conditions. [1] Helium's first ionization energy of 24.57 eV is the highest of any element. [2]
Atomicity is the total number of atoms present in a molecule of an element. For example, each molecule of oxygen (O 2) is composed of two oxygen atoms.Therefore, the atomicity of oxygen is 2.
A diatomic gas is axially symmetric about only one axis, so that D = 5, comprising translational motion along three axes and rotational motion along two axes. A polyatomic gas, like water, is not radially symmetric about any axis, resulting in D = 6, comprising 3 translational and 3 rotational degrees of freedom.
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A diatomic molecular orbital diagram is used to understand the bonding of a diatomic molecule. MO diagrams can be used to deduce magnetic properties of a molecule and how they change with ionization. They also give insight to the bond order of the molecule, how many bonds are shared between the two atoms. [12]