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  2. Second law of thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Second_law_of_thermodynamics

    The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions.A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).

  3. Laws of thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Laws_of_thermodynamics

    The first established thermodynamic principle, which eventually became the second law of thermodynamics, was formulated by Sadi Carnot in 1824 in his book Reflections on the Motive Power of Fire. By 1860, as formalized in the works of scientists such as Rudolf Clausius and William Thomson , what are now known as the first and second laws were ...

  4. Thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equations

    The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.

  5. Thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Thermodynamics

    The zeroth law was not initially recognized as a separate law of thermodynamics, as its basis in thermodynamical equilibrium was implied in the other laws. The first, second, and third laws had been explicitly stated already, and found common acceptance in the physics community before the importance of the zeroth law for the definition of ...

  6. Entropy as an arrow of time - Wikipedia

    en.wikipedia.org/wiki/Entropy_as_an_arrow_of_time

    The second law of thermodynamics is statistical in nature, and therefore its reliability arises from the huge number of particles present in macroscopic systems. It is not impossible, in principle, for all 6 × 10 23 atoms in a mole of a gas to spontaneously migrate to one half of a container; it is only fantastically unlikely—so unlikely ...

  7. Principle of minimum energy - Wikipedia

    en.wikipedia.org/wiki/Principle_of_minimum_energy

    The principle of minimum energy is essentially a restatement of the second law of thermodynamics. It states that for a closed system, with constant external parameters and entropy, the internal energy will decrease and approach a minimum value at equilibrium. External parameters generally means the volume, but may include other parameters which ...

  8. Maxwell's demon - Wikipedia

    en.wikipedia.org/wiki/Maxwell's_demon

    Maxwell's demon is a thought experiment that appears to disprove the second law of thermodynamics. It was proposed by the physicist James Clerk Maxwell in 1867. [1] In his first letter, Maxwell referred to the entity as a "finite being" or a "being who can play a game of skill with the molecules". Lord Kelvin would later call it a "demon". [2]

  9. Heat pump and refrigeration cycle - Wikipedia

    en.wikipedia.org/wiki/Heat_pump_and...

    According to the second law of thermodynamics, heat cannot spontaneously flow from a colder location to a hotter area; work is required to achieve this. [4] An air conditioner requires work to cool a living space, moving heat from the interior being cooled (the heat source) to the outdoors (the heat sink).