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"Redox" is a portmanteau of the words "REDuction" and "OXidation." The term "redox" was first used in 1928. [6] Oxidation is a process in which a substance loses electrons. Reduction is a process in which a substance gains electrons. The processes of oxidation and reduction occur simultaneously and cannot occur independently. [5]
In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
Organic redox reactions: the Birch reduction. Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds.In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer. [1]
The mechanism of ·OH production (Part 1) highly depends on the sort of AOP technique that is used. For example, ozonation, UV/H 2 O 2, photocatalytic oxidation and Fenton's oxidation rely on different mechanisms of ·OH generation: UV/H 2 O 2: [6] [12] [13] H 2 O 2 + UV → 2·OH (homolytic bond cleavage of the O-O bond of H 2 O 2 leads to ...
Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands. It is the microscopic reverse of oxidative addition, and is often the product-forming step in many catalytic processes. Since oxidative addition and reductive ...
An agent's oxidation state describes its degree of loss of electrons, where the higher the oxidation state then the fewer electrons it has. So initially, prior to the reaction, a reducing agent is typically in one of its lower possible oxidation states; its oxidation state increases during the reaction while that of the oxidizer decreases.
For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H + ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH − ...
The oxygen reduction reaction is an essential reaction for aerobic organisms. Such organisms are powered by the heat of combustion of fuel (food) by O 2.Rather than combustion, organisms rely on elaborate sequences of electron-transfer reactions, often coupled to proton transfer.