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In other words, the strain energy density function can be expressed uniquely in terms of the principal stretches or in terms of the invariants of the left Cauchy–Green deformation tensor or right Cauchy–Green deformation tensor and we have: For isotropic materials,
The reaction will proceed towards the lower energy - reducing for the blue curve, oxidizing for the red curve. The green curve illustrates equilibrium. The following derivation of the extended Butler–Volmer equation is adapted from that of Bard and Faulkner [3] and Newman and Thomas-Alyea. [5] For a simple unimolecular, one-step reaction of ...
The higher the energy density of the fuel, the more energy may be stored or transported for the same amount of volume. The energy of a fuel per unit mass is called its specific energy. The adjacent figure shows the gravimetric and volumetric energy density of some fuels and storage technologies (modified from the Gasoline article).
The locus of these points (the inflection point within a G-x or G-c curve, Gibbs free energy as a function of composition) is known as the spinodal curve. [1] [2] [3] For compositions within this curve, infinitesimally small fluctuations in composition and density will lead to phase separation via spinodal decomposition.
The total energy density U can be similarly calculated, except the integration is over the whole sphere and there is no cosine, and the energy flux (U c) should be divided by the velocity c to give the energy density U: = (,) Thus / is replaced by , giving an extra factor of 4.
In fracture mechanics, the energy release rate, , is the rate at which energy is transformed as a material undergoes fracture.Mathematically, the energy release rate is expressed as the decrease in total potential energy per increase in fracture surface area, [1] [2] and is thus expressed in terms of energy per unit area.
In the case of degenerate energy levels, we can write the partition function in terms of the contribution from energy levels (indexed by j) as follows: =, where g j is the degeneracy factor, or number of quantum states s that have the same energy level defined by E j = E s.
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume: