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Acetic acid: ethanoic acid CH 3 CO 2 H ... 2-hydroxy-1,2,3-propanetricarboxylic acid: HOC ... CH 3 CH=CHC 4 H 8 COOH 7-octenoic acid CH 2 =CHC 5 H 10 COOH
Ethyl glyoxylate 2 and glutaconate (diethyl-2-methylpent-2-enedioate) 1 react to isoprenetricarboxylic acid 3 (isoprene (2-methylbuta-1,3-diene) skeleton) with sodium ethoxide. This reaction product is very unstable with initial loss of carbon dioxide and followed by many secondary reactions.
C 2 H 8 N 2: 1,1-dimethylhydrazine: 57-14-7 C 2 H 8 N 2: 1,2-dimethylhydrazine: 540-73-8 (CH 3) 2 SO: dimethyl sulfoxide: 67-68-5 C 4 H 8 O 2: 1,4-Dioxane: 123-91-1 C 2 H 6 O: ethanol: 64-17-5 CH 3 CH 2 NH 2: ethylamine: 75-04-7 C 2 H 6 O 2: ethylene glycol: 107-21-1 HCOOH: formic acid: 64-18-6 C 5 H 6 O 2: furfuryl alcohol: 98-00-0 C 3 H 8 O 3 ...
The active hydrogen component has the forms: [3] Z−CH 2 −Z or Z−CHR−Z for instance diethyl malonate, Meldrum's acid, ethyl acetoacetate or malonic acid, or cyanoacetic acid. [1] Z−CHRR', for instance nitromethane. where Z is an electron withdrawing group. Z must be powerful enough to facilitate deprotonation to the enolate ion even ...
The reaction consists of ethylene and acetic acid with oxygen over a palladium catalyst, conducted in the gas phase. [49] 2 H 3 C−COOH + 2 C 2 H 4 + O 2 → 2 H 3 C−CO−O−CH=CH 2 + 2 H 2 O. Vinyl acetate can be polymerised to polyvinyl acetate or other polymers, which are components in paints and adhesives. [49]
One family of Cr(VI) reagents employs the complex CrO 3 (pyridine) 2. [3] Sarett's reagent: a solution of CrO 3 (pyridine) 2 in pyridine. It was popularized for selective oxidation of primary and secondary alcohols to carbonyl compounds. Collins reagent is a solution of the same CrO 3 (pyridine) 2 but in dichloromethane. The Ratcliffe variant ...
To selectively form the allyl alcohol and avoid the 1,4 product, the Luche reduction uses "cerium borohydride" generated in situ from NaBH 4 and CeCl 3 (H 2 O) 7 [21] [22] The hydride source Zn(BH 4) 2 also shows 1,2 selectivity, as well as greater diastereoselectivity.
When necessary, the position of the hydroxyl group is indicated by a number between the alkane name and the -ol: propan-1-ol for CH 3 CH 2 CH 2 OH, propan-2-ol for CH 3 CH(OH)CH 3. If a higher priority group is present (such as an aldehyde , ketone , or carboxylic acid ), then the prefix hydroxy- is used, [ 19 ] e.g., as in 1-hydroxy-2 ...