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, Ca 2+, and Sc 3+ and the anions Cl −, S 2−, and P 3− are all isoelectronic with the Ar atom. CO, CN −, N 2, and NO + are isoelectronic because each has two atoms triple bonded together, and due to the charge have analogous electronic configurations (N − is identical in electronic configuration to O so CO is identical electronically ...
Isolobal compounds are analogues to isoelectronic compounds that share the same number of valence electrons and structure. A graphic representation of isolobal structures, with the isolobal pairs connected through a double-headed arrow with half an orbital below, is found in Figure 1. Figure 1: Basic example of the isolobal analogy
Broken Cooper pair electron, hole Composite fermion: Arise in a two-dimensional system subject to a large magnetic field, most famously those systems that exhibit the fractional quantum Hall effect. [4] electron Configuron [5] An elementary configurational excitation in an amorphous material which involves breaking of a chemical bond Cooper pair
As introduced by Gerhard Herzberg, [1] building off of work by R. S. Mulliken and Friedrich Hund, bond order is defined as the difference between the numbers of electron pairs in bonding and antibonding molecular orbitals. Bond order gives a rough indication of the stability of a bond. Isoelectronic species have the same bond order. [2]
Example: C 2 B 7 H 13. Electron count = 2 × C + 7 × B + 13 × H = 2 × 4 + 7 × 3 + 13 × 1 = 42 Since n in this case is 9, 4n + 6 = 42, the cluster is arachno. The bookkeeping for deltahedral clusters is sometimes carried out by counting skeletal electrons instead of the total number of electrons.
In physics, mirror nuclei are a pair of isobars of two different elements where the number of protons of isobar one (Z 1) equals the number of neutrons of isobar two (N 2) and the number of protons of isotope two (Z 2) equals the number of neutrons in isotope one (N 1); in short: Z 1 = N 2 and Z 2 = N 1.
This increased p character in those orbitals decreases the bond angle between them to less than the tetrahedral 109.5°. The same logic can be applied to ammonia (107.0° HNH bond angle, with three N(~sp 3.4 or 23% s) bonding orbitals and one N(~sp 2.1 or 32% s) lone pair), the other canonical example of this phenomenon.
In this example, the cyanide ligands are "innocent", i.e., they have a charge of −1 each, −5 total. To balance the fragment's overall charge, the charge on {CrNO} is thus +2 (−3 = −5 + 2). Using the neutral electron counting scheme, Cr has 6 d electrons and NO· has one electron for a total of 7. Two electrons are subtracted to take ...