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Isoelectronic species can be expected to show useful consistency and predictability in their properties, so identifying a compound as isoelectronic with one already characterised offers clues to possible properties and reactions. Differences in properties such as electronegativity of the atoms in isolelectronic species can affect reactivity.
A hydrogen-like atom (or hydrogenic atom) is any atom or ion with a single valence electron.These atoms are isoelectronic with hydrogen.Examples of hydrogen-like atoms include, but are not limited to, hydrogen itself, all alkali metals such as Rb and Cs, singly ionized alkaline earth metals such as Ca + and Sr + and other ions such as He +, Li 2+, and Be 3+ and isotopes of any of the above.
Atoms that lose electrons make positively charged ions (called cations). This transfer of electrons is known as electrovalence in contrast to covalence . In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be more complex, e.g. polyatomic ions like NH +
The tetrafluoroammonium cation (also known as perfluoroammonium) is a positively charged polyatomic ion with chemical formula NF + 4. It is equivalent to the ammonium ion where the hydrogen atoms surrounding the central nitrogen atom have been replaced by fluorine. [1] Tetrafluoroammonium ion is isoelectronic with tetrafluoromethane CF 4 ...
Zintl ions can oxidize without the presence of specific oxidizing agents through solvent molecules or impurities, for example in the presence of cryptand, which is often used to aid crystallization. [15] Zintl ion clusters can be functionalized with a variety of ligands in a similar reaction to their oligomerization. As such, functionalization ...
Many other compounds with quadruple bonds between transition metal atoms have been described, often by Cotton and his coworkers. Isoelectronic with the dirhenium compound is the salt K 4 [Mo 2 Cl 8] (potassium octachlorodimolybdate). [7] An example of a ditungsten compound with a quadruple bond is ditungsten tetra(hpp).
With other atoms, fluorine forms either polar covalent bonds or ionic bonds. ... and a few polyatomic ions: the very unstable anions F ... It is isoelectronic with N ...
Compounds which are isoelectronic usually have similar chemical structures. For example, methane, CH 4, and the ammonium ion, NH 4 +, are isoelectric and are isostructural as both have a tetrahedral structure. The C-H and N-H bond lengths are different and crystal structures are completely different because the ammonium ion only occurs in salts.