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Monoatomic (composed of one atom). Examples include He , Ne , Ar , and Kr . All noble gases are monoatomic. Diatomic (composed of two atoms). Examples include H 2 , N 2 , O 2 , F 2 , and Cl 2 . Halogens are usually diatomic. Triatomic (composed of three atoms). Examples include O 3 .
It is usually applied to gases: a monatomic gas is a gas in which atoms are not bound to each other. Examples at standard conditions of temperature and pressure include all the noble gases ( helium , neon , argon , krypton , xenon , and radon ), though all chemical elements will be monatomic in the gas phase at sufficiently high temperature (or ...
Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
For simple polyatomic molecules with a "central atom" such as methane (CH 4) or carbon dioxide (CO 2), a MO diagram may show one of the identical bonds to the central atom. For other polyatomic molecules, an MO diagram may show one or more bonds of interest in the molecules, leaving others out for simplicity.
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).
Monatomic gas heat capacities per atom (not per molecule) are decreased by a factor of 2 with regard to solids, due to loss of half of the potential degrees of freedom per atom for storing energy in a monatomic gas, as compared with regard to an ideal solid. There is some difference in the heat capacity of monatomic vs. polyatomic gasses, and ...
One way to look at this result is to observe that the monatomic gas can only store energy as kinetic energy of the atoms, whereas the solid can store it also as potential energy of the bonds strained by the vibrations. The atom-molar heat capacity of a polyatomic gas approaches that of a solid as the number n of atoms per molecule increases.