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White phosphorus, yellow phosphorus, or simply tetraphosphorus (P 4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus ), [ 2 ] and impure white phosphorus is for this reason called yellow phosphorus.
The highest-grade deposits were found where weathering or shallow groundwater had preferentially dissolved away the calcium carbonate. The last mine in Tennessee, which produced phosphate rock from the Bigby-Cannon formation, closed in 1991. The blue phosphate rock was found in the Devonian-age Chattanooga Shale.
The Bone Valley is a region of central Florida, encompassing portions of present-day Hardee, Hillsborough, Manatee, and Polk counties, in which phosphate is mined for use in the production of agricultural fertilizer. Florida currently contains the largest known deposits of phosphate in the United States.
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Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth. It has an occurrence in the Earth's crust of about 0.1%, generally occurring as phosphate in minerals.
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The Phosphoria includes phosphorite beds that are an important source of phosphorus. [5] Many of its shales are rich in organic matter and are petroleum source rocks , [ 6 ] and some of its dolomites include petroleum reservoirs .
A U.S.-led military coalition also deployed white phosphorus weapons in Syria and Iraq in its war against ISIS in 2017, according to HRW. Israel, too, previously used the substance during a 2008 ...