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Benzenesulfonic acid (conjugate base benzenesulfonate) is an organosulfur compound with the formula C 6 H 6 O 3 S. It is the simplest aromatic sulfonic acid . It forms white deliquescent sheet crystals or a white waxy solid that is soluble in water and ethanol , slightly soluble in benzene and insoluble in nonpolar solvents like diethyl ether .
By measuring the pK a at various ionic strengths and extrapolating to zero ionic strength, the pK a of phenylsulfinic acid was determined to be 2.76. [1] This makes phenylsulfinic acid a stronger acid than its corresponding carboxylic acid, benzoic acid (pK a = 4.2), but weaker than its corresponding sulfonic acid, benzenesulfonic acid (pK a ...
In the most common route benzene is alkylated by long chain monoalkenes (e.g. dodecene) using hydrogen fluoride as a catalyst. [9] The purified dodecylbenzenes (and related derivatives) are then sulfonated with sulfur trioxide to give the sulfonic acid. [10] The sulfonic acid is subsequently neutralized with sodium hydroxide. [1]
The approach exploits the meta-directing effect of the sulfonic acid group. 2-Chlorotoluene for example can be prepared by chlorination of p-toluenesulfonic acid , followed by hydrolysis. The method is also useful for the preparation of 2,6- dinitroaniline [ 3 ] and 2-bromophenol via phenol-2,4-disulfonic acid.
Phenol (also known as carbolic acid, phenolic acid, or benzenol) is an aromatic organic compound with the molecular formula C 6 H 5 OH. [5] It is a white crystalline solid that is volatile. The molecule consists of a phenyl group (−C 6 H 5) bonded to a hydroxy group (−OH). Mildly acidic, it requires careful handling because it can cause ...
Sodium benzenesulfonate is an organic compound with the formula C 6 H 5 SO 3 Na.It is white, water-soluble solid, It is produced by the neutralization benzenesulfonic acid with sodium hydroxide.