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One use of conjugate acids and bases lies in buffering systems, which include a buffer solution. In a buffer, a weak acid and its conjugate base (in the form of a salt), or a weak base and its conjugate acid, are used in order to limit the pH change during a titration process. Buffers have both organic and non-organic chemical applications.
2 HSO − 3 S 2 O 2− 5 + H 2 O. Although the equilibrium lies far to the left, evaporation of a bisulfite salt will produce a substantial amount of disulfite. [6] Disulfite is the conjugate base of disulfurous acid (pyrosulfurous acid), which originates from sulfurous acid in accordance with the dehydration reaction above: 2 H 2 SO 3 → 2 ...
The sulfide ion does not exist in aqueous alkaline solutions of Na 2 S. [3] [4] Instead sulfide converts to hydrosulfide: S 2− + H 2 O → SH − + OH −. Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: S 2− + H + → SH − SH − + H + → H 2 S. Oxidation of sulfide is a complicated process.
Its conjugate acid is hydrogen sulfide (H 2 S). However, bisulfide's basicity stems from its behavior as an Arrhenius base . A solution containing spectator-only counter ions, has a basic pH according to the following acid-base reaction:
For example, pK a for HClO is 7.2, for HClO 2 is 2.0, for HClO 3 is −1 and HClO 4 is a strong acid (pK a ≪ 0). [7] The increased acidity on adding an oxo group is due to stabilization of the conjugate base by delocalization of its negative charge over an additional oxygen atom. [ 47 ]
Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
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2 O 2− 8, is an oxyanion, the anion of peroxydisulfuric acid. It is commonly referred to as persulfate, but this term also refers to the peroxomonosulfate ion, SO 2− 5. It is also called peroxodisulfate. [2] Approximately 500,000 tons of salts containing this anion are produced annually.