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The phase space can also refer to the space that is parameterized by the macroscopic states of the system, such as pressure, temperature, etc. For instance, one may view the pressure–volume diagram or temperature–entropy diagram as describing part of this phase space. A point in this phase space is correspondingly called a macrostate.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
Low-pressure phase diagram of pure iron. BCC is body centered cubic and FCC is face-centered cubic. Iron-carbon eutectic phase diagram, showing various forms of Fe x C y substances. Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC).
Spinodal decomposition. Microstructural evolution under the Cahn–Hilliard equation, demonstrating distinctive coarsening and phase separation. Spinodal decomposition is a mechanism by which a single thermodynamic phase spontaneously separates into two phases (without nucleation). [1] Decomposition occurs when there is no thermodynamic barrier ...
Phase rule. In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (p), volume (V) and temperature (T), in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then.
Spinodal. A phase diagram displaying spinodal curves, within the binodal coexistence curves and two critical points: an upper and lower critical solution temperature. In thermodynamics, the limit of local stability against phase separation with respect to small fluctuations is clearly defined by the condition that the second derivative of Gibbs ...
Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. [1] In plain-carbon steel , austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures.
In condensed matter physics, dealing with the macroscopic physical properties of matter, a tricritical point is a point in the phase diagram of a system at which three-phase coexistence terminates. [4] This definition is clearly parallel to the definition of an ordinary critical point as the point at which two-phase coexistence terminates.