Search results
Results From The WOW.Com Content Network
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
Diagram illustrating the image method for Laplace's equation for a sphere of radius R. The green point is a charge q lying inside the sphere at a distance p from the origin, the red point is the image of that point, having charge −qR/p, lying outside the sphere at a distance of R 2 /p from the origin. The potential produced by the two charges ...
The full form of the J-coupling interaction between spins 'I j and I k on the same molecule is: H = 2π I j · J jk · I k. where J jk is the J-coupling tensor, a real 3 × 3 matrix. It depends on molecular orientation, but in an isotropic liquid it reduces to a number, the so-called scalar coupling. In 1D NMR, the scalar coupling leads to ...
A polariton is the result of the combination of a photon with a polar excitation in a material. The following are types of polaritons: Phonon polaritons result from coupling of an infrared photon with an optical phonon
A dipole graph containing n edges is called the size-n dipole graph, and is denoted by D n. The size-n dipole graph is dual to the cycle graph C n. The honeycomb as an abstract graph is the maximal abelian covering graph of the dipole graph D 3, while the diamond crystal as an abstract graph is the maximal abelian covering graph of D 4.
The most important example in organic chemistry is observation of 13 C while decoupling 1 H, which also saturates the 1 J resonances. The value of γ S / γ I is close to 4, which gives a maximum NOE enhancement of 200% yielding resonances 3 times as strong as they would be without NOE. [ 15 ]
By truncating this expansion (for example, retaining only the dipole terms, or only the dipole and quadrupole terms, or etc.), the results of the previous section are regained. In particular, truncating the expansion at the dipole term, the result is indistinguishable from the polarization density generated by a uniform dipole moment confined ...
For example, NO 2 − is a strong-field ligand and produces a large Δ. The octahedral ion [Fe(NO 2 ) 6 ] 3− , which has 5 d -electrons, would have the octahedral splitting diagram shown at right with all five electrons in the t 2 g level.