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Arsenic trisulfide is the inorganic compound with the formula As 2 S 3. It is a dark yellow solid that is insoluble in water. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow.
Arsenic sulfide may refer to: Arsenic trisulfide , As 2 S 3 , the mineral orpiment Arsenic pentasulfide , As 2 S 5 , similar structure to phosphorus pentasulfide (β-P 2 S 5 )
In organic and organometallic chemistry, trisulfide is the functional group R-S-S-S-R. Examples include: Diallyl trisulfide; Dimethyl trisulfide; Trisulfane (hydrogen trisulfide) Some inorganic compounds are also named trisulfides to reflect their stoichiometry. Examples include: Antimony trisulfide; Arsenic trisulfide; Bismuth trisulfide ...
Arsenic trioxide powder.. Compounds of arsenic resemble in some respects those of phosphorus which occupies the same group (column) of the periodic table.The most common oxidation states for arsenic are: −3 in the arsenides, which are alloy-like intermetallic compounds, +3 in the arsenites, and +5 in the arsenates and most organoarsenic compounds.
The Marsh test treats the sample with sulfuric acid and arsenic-free zinc. Even if there are minute amounts of arsenic present, the zinc reduces the trivalent arsenic (As 3+). Here are the two half-reactions: Oxidation: Zn → Zn 2+ + 2 e − Reduction: As 2 O 3 + 12 e − + 6 H + → 2 As 3− + 3 H 2 O. Overall, we have this reaction:
While he was able to detect arsenic as yellow arsenic trisulfide, when it came to showing it to the jury it had deteriorated, allowing the suspect to be acquitted due to reasonable doubt. Annoyed by this, Marsh developed a much better test. He combined a sample containing arsenic with sulfuric acid and arsenic-free zinc, resulting in arsine gas ...
The determination of arsenic(V) compounds is the reverse of the standardization of iodine solution with sodium arsenite, where a known and excess amount of iodide is added to the sample: As 2 O 5 + 4 H + + 4 I − ⇌ As 2 O 3 + 2 I 2 + 2 H 2 O. For analysis of antimony(V) compounds, some tartaric acid is added to solubilize the antimony(III ...
Arsenic pentasulfide is prepared by precipitation from an acidic solution of soluble As(V) salts by treatment with hydrogen sulfide. [3] It may be also prepared by heating a mixture of arsenic and sulfur, extracting the fused mass with an ammonia solution and reprecipitating arsenic pentasulfide at low temperature by addition of hydrochloric acid.