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The constitutive equations describe how the quantity in question responds to various stimuli via transport. Prominent examples include Fourier's law of heat conduction and the Navier–Stokes equations , which describe, respectively, the response of heat flux to temperature gradients and the relationship between fluid flux and the forces ...
In physical chemistry, the Evans–Polanyi principle (also referred to as the Bell–Evans–Polanyi principle, Brønsted–Evans–Polanyi principle, or Evans–Polanyi–Semenov principle) observes that the difference in activation energy between two reactions of the same family is proportional to the difference of their enthalpy of reaction.
A force field is used to minimize the bond stretching energy of this ethane molecule. Molecular mechanics uses classical mechanics to model molecular systems. The Born–Oppenheimer approximation is assumed valid and the potential energy of all systems is calculated as a function of the nuclear coordinates using force fields. Molecular ...
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This discipline covers topics such as the measurement of molecular forces, molecular associations, allosteric interactions, Brownian motion, and cable theory. [2] Additional areas of study can be found on Outline of Biophysics. The discipline has required development of specialized equipment and procedures capable of imaging and manipulating ...
The induced dipole forces appear from the induction (also termed polarization), which is the attractive interaction between a permanent multipole on one molecule with an induced (by the former di/multi-pole) 31 on another. [12] [13] [14] This interaction is called the Debye force, named after Peter J. W. Debye.
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The driving forces for such reaction is the electron donating abilities of the radical sites: N > S, O,π > Cl, Br > H. [11] An example is the cleavage of carbon-carbon bonds next to a heteroatom. In this depiction, single-electron movements are indicated by a single-headed arrow .