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Theoretical isotope distribution for the molecular ion of caffeine. The molecular mass (abbreviated M r) of a substance, formerly also called molecular weight and abbreviated as MW, is the mass of one molecule of that substance, relative to the unified atomic mass unit u (equal to 1/12 the mass of one atom of 12 C).
Relative atomic mass is determined by the average atomic mass, or the weighted mean of the atomic masses of all the atoms of a particular chemical element found in a particular sample, which is then compared to the atomic mass of carbon-12. [10] This comparison is the quotient of the two weights, which makes the value dimensionless (having no ...
Thus, molecular mass and molar mass differ slightly in numerical value and represent different concepts. Molecular mass is the mass of a molecule, which is the sum of its constituent atomic masses. Molar mass is an average of the masses of the constituent molecules in a chemically pure but isotopically heterogeneous ensemble.
The new unit was named the "unified atomic mass unit" and given a new symbol "u", to replace the old "amu" that had been used for the oxygen-based unit. [17] However, the old symbol "amu" has sometimes been used, after 1961, to refer to the new unit, particularly in lay and preparatory contexts.
The mass number should also not be confused with the standard atomic weight (also called atomic weight) of an element, which is the ratio of the average atomic mass of the different isotopes of that element (weighted by abundance) to the atomic mass constant. [9]
The monoisotopic mass is not used frequently in fields outside of mass spectrometry because other fields cannot distinguish molecules of different isotopic composition. For this reason, mostly the average molecular mass or even more commonly the molar mass is used. For most purposes such as weighing out bulk chemicals only the molar mass is ...
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The molar mass is an average of many instances of the compound, which often vary in mass due to the presence of isotopes. Most commonly, the molar mass is computed from the standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the isotopes of the constituent atoms on Earth. The molar mass is ...