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Acetic anhydride, like most organic acid anhydrides, is a flexible molecule with a nonplanar structure. [4] The pi system linkage through the central oxygen offers very weak resonance stabilization compared to the dipole-dipole repulsion between the two carbonyl oxygens.
D-glucose is first protected by forming the peracetate by addition of acetic anhydride in acetic acid, and then addition of hydrogen bromide which brominates at the 5-position. On addition of the alcohol ROH and lithium carbonate, the OR replaces the bromine and on deprotecting the acetylated hydroxyls the product is synthesized in relatively ...
However, acetic acid is usually also formed as a by-product of the reaction, so that the solvent is ultimately a mixture of methylene chloride, acetic anhydride and acetic acid. A very rare heterogeneous process is the fiber acetate process, which is only used for the production of cellulose triacetate as an end product.
A common type of organic acid anhydride is a carboxylic anhydride, where the parent acid is a carboxylic acid, the formula of the anhydride being (RC(O)) 2 O. Symmetrical acid anhydrides of this type are named by replacing the word acid in the name of the parent carboxylic acid by the word anhydride. [2] Thus, (CH 3 CO) 2 O is called acetic ...
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N-Acetylglucosamine molecule. N-Acetylglucosamine (GlcNAc) is an amide derivative of the monosaccharide glucose.It is a secondary amide between glucosamine and acetic acid.It is significant in several biological systems.
Dextrose monohydrate is the hydrated form of D-glucose, meaning that it is a glucose molecule with an additional water molecule attached. [39] Its chemical formula is C 6 H 12 O 6 · H 2 O. [39] [40] Dextrose monohydrate is also called hydrated D-glucose, and commonly manufactured from plant starches.
Typically anhydrous solvents will contain approximately 10 ppm of water and will increase in wetness if they are not properly stored. Organic solutions can be dried using a range of drying agents . Typically following a workup the organic extract is dried using magnesium sulfate or a similar drying agent to remove most remaining water.