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The Rayleigh sky model describes the observed polarization pattern of the daytime sky. Within the atmosphere, Rayleigh scattering of light by air molecules, water, dust, and aerosols causes the sky's light to have a defined polarization pattern. The same elastic scattering processes cause the sky to be blue.
Rayleigh scattering of that light off oxygen and nitrogen molecules, and; the response of the human visual system. The strong wavelength dependence of the Rayleigh scattering (~λ −4) means that shorter wavelengths are scattered more strongly than longer wavelengths. This results in the indirect blue and violet light coming from all regions ...
Hyper–Rayleigh scattering optical activity (/ ˈ r eɪ l i / RAY-lee), a form of chiroptical harmonic scattering, is a nonlinear optical physical effect whereby chiral scatterers (such as nanoparticles or molecules) convert light (or other electromagnetic radiation) to higher frequencies via harmonic generation processes, in a way that the ...
Mie scattering (sometimes referred to as a non-molecular scattering or aerosol particle scattering) takes place in the lower 4,500 m (15,000 ft) of the atmosphere, where many essentially spherical particles with diameters approximately equal to the wavelength of the incident ray may be present. Mie scattering theory has no upper size limitation ...
Both Mie and Rayleigh scattering are considered elastic scattering processes, in which the energy (and thus wavelength and frequency) of the light is not substantially changed. However, electromagnetic radiation scattered by moving scattering centers does undergo a Doppler shift , which can be detected and used to measure the velocity of the ...
Thus, speckle and resonant Rayleigh-scattering are always superimposed to the incoherent emission. In case of the non-resonant excitation, the structure is excited with some excess energy. This is the typical situation used in most PL experiments as the excitation energy can be discriminated using a spectrometer or an optical filter. One has to ...
Mathematically, for the spectral power distribution of a radiant exitance or irradiance one may write: =where M(λ) is the spectral irradiance (or exitance) of the light (SI units: W/m 2 = kg·m −1 ·s −3); Φ is the radiant flux of the source (SI unit: watt, W); A is the area over which the radiant flux is integrated (SI unit: square meter, m 2); and λ is the wavelength (SI unit: meter, m).
Energy level diagram showing relationship between Rayleigh, Raman, and resonance Raman scattering and fluorescence. Resonance Raman spectroscopy (RR spectroscopy or RRS) is a variant of Raman spectroscopy in which the incident photon energy is close in energy to an electronic transition of a compound or material under examination. [1]