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Rayleigh scattering causes the blue color of the daytime sky and the reddening of the Sun at sunset. Rayleigh scattering (/ ˈ r eɪ l i / RAY-lee) is the scattering or deflection of light, or other electromagnetic radiation, by particles with a size much smaller than the wavelength of the radiation.
The Rayleigh sky model describes the observed polarization pattern of the daytime sky. Within the atmosphere, Rayleigh scattering of light by air molecules, water, dust, and aerosols causes the sky's light to have a defined polarization pattern. The same elastic scattering processes cause the sky to be blue.
Scattering of light and radio waves (especially in radar) is particularly important. Several different aspects of electromagnetic scattering are distinct enough to have conventional names. Major forms of elastic light scattering (involving negligible energy transfer) are Rayleigh scattering and Mie scattering.
The elastic light scattering phenomena called Rayleigh scattering, in which light retains its energy, was described in the 19th century. The intensity of Rayleigh scattering is about 10 −3 to 10 −4 compared to the intensity of the exciting source. [2] In 1908, another form of elastic scattering, called Mie scattering was discovered.
Multiple-scattering effects of light scattering by particles are treated by radiative transfer techniques (see, e.g. atmospheric radiative transfer codes). The relative size of a scattering particle is defined by its size parameter x, which is the ratio of its characteristic dimension to its wavelength:
The figure depicts three important details. The first is the Rayleigh line, the peak which has been suppressed at 0 cm −1. This peak is a result of Rayleigh scattering, a form of elastic scattering from the incident photons and the sample. Rayleigh scattering occurs when the induced polarization of the atoms, resulting from the incident ...
Thus, speckle and resonant Rayleigh-scattering are always superimposed to the incoherent emission. In case of the non-resonant excitation, the structure is excited with some excess energy. This is the typical situation used in most PL experiments as the excitation energy can be discriminated using a spectrometer or an optical filter. One has to ...
The dominant radiative scattering processes in the atmosphere are Rayleigh scattering and Mie scattering; they are elastic, meaning that a photon of light can be deviated from its path without being absorbed and without changing wavelength. Under an overcast sky, there is no direct sunlight, and all light results from diffused skylight radiation.