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In chemistry, fractional crystallization is a stage-wise separation technique that relies on the liquid–solid phase change. This technique fractionates via differences in crystallization temperature and enables the purification of multi-component mixtures, as long as none of the constituents can act as solvents to the others. Due to the high ...
Crystallization occurs in two major steps. The first is nucleation, the appearance of a crystalline phase from either a supercooled liquid or a supersaturated solvent. The second step is known as crystal growth, which is the increase in the size of particles and leads to a crystal state. An important feature of this step is that loose particles ...
Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation . [ 1 ]
Within the field of geology, Bowen's reaction series is the work of the Canadian petrologist Norman L. Bowen, [1] who summarized, based on experiments and observations of natural rocks, the sequence of crystallization of common silicate minerals from typical basaltic magma undergoing fractional crystallization (i.e. crystallization wherein early-formed crystals are removed from the magma by ...
Two more allotropes, γ and σ, exist at temperatures above 161 °C and pressures above several GPa. [23] White tin is metallic, and is the stable crystalline form at or above room temperature. Below 13.2 °C, tin exists in the gray form, which has a diamond cubic crystal structure, similar to diamond, silicon or germanium.
Fractional crystallization may refer to: Fractional crystallization (chemistry) , a process to separate different solutes from a solution Fractional crystallization (geology) , a natural process occurring in igneous rocks during which precipitation of minerals takes place
[1] [2] Fractions are collected based on differences in a specific property of the individual components. A common trait in fractionations is the need to find an optimum between the amount of fractions collected and the desired purity in each fraction. Fractionation makes it possible to isolate more than two components in a mixture in a single run.
Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. [1] [2] Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation ...