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Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa ), which is equivalent to 1,013.25 millibars , [ 1 ] 760 mm Hg , 29.9212 inches Hg , or 14.696 psi . [ 2 ]
Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant. Therefore, when the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved.
at each geopotential altitude, where g is the standard acceleration of gravity, and R specific is the specific gas constant for dry air (287.0528J⋅kg −1 ⋅K −1). The solution is given by the barometric formula. Air density must be calculated in order to solve for the pressure, and is used in calculating dynamic pressure for moving vehicles.
where c p is the specific heat capacity for a constant pressure and c v is the specific heat capacity for a constant volume. [9] It is common, especially in engineering applications, to represent the specific gas constant by the symbol R. In such cases, the universal gas constant is usually given a different symbol such as R to distinguish it ...
where H = U + PV is the enthalpy of the gas. Sometimes, a distinction is made between an ideal gas, where ĉ V and ĉ P could vary with temperature, and a perfect gas, for which this is not the case. The ratio of the constant volume and constant pressure heat capacity is the adiabatic index =
ρ (Greek letter rho) is the fluid mass density (e.g. in kg/m 3), and; u is the flow speed in m/s. It can be thought of as the fluid's kinetic energy per unit volume. For incompressible flow, the dynamic pressure of a fluid is the difference between its total pressure and static pressure. From Bernoulli's law, dynamic pressure is given by
Once the constants and are experimentally determined for a given substance, the van der Waals equation can be used to predict attributes like the boiling point at any given pressure, and the critical point (defined by pressure and temperature such that the substance cannot be liquefied either when > no matter how low the temperature, or when ...