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Dialysis is the process used to change the matrix of molecules in a sample by differentiating molecules by the classification of size. [6] [7] It relies on diffusion, which is the random, thermal movement of molecules in solution (Brownian motion) that leads to the net movement of molecules from an area of higher concentration to a lower concentration until equilibrium is reached.
Multicomponent diffusion is diffusion in mixtures, and diffusiophoresis is the special case where we are interested in the movement of one species that is usually a colloidal particle, in a gradient of a much smaller species, such as dissolved salt such as sodium chloride in water. or a miscible liquid, such as ethanol in water.
The concept of diffusion is widely used in many fields, including physics (particle diffusion), chemistry, biology, sociology, economics, statistics, data science, and finance (diffusion of people, ideas, data and price values). The central idea of diffusion, however, is common to all of these: a substance or collection undergoing diffusion ...
In the case of dialysis, the driving concentration gradient in the membrane is reduced. [6] In the case of electromembrane processes, the potential drop in the diffusion boundary layers reduces the gradient of electric potential in the membrane. Lower rate of separation under the same external driving force means increased power consumption.
Dialysis tubing, also known as Visking tubing, is an artificial semi-permeable membrane tubing [1] used in separation techniques, that facilitates the flow of tiny molecules in solution based on differential diffusion. In the context of life science research, dialysis tubing is typically used in the sample clean-up and processing of proteins ...
Matteucci's frog battery, 1845 (top left); Aldini's frog battery, 1818 (bottom); apparatus for controlled exposure of gases to frog battery (top right). A frog battery is an electrochemical battery consisting of a number of dead frogs (or sometimes live ones), which form the cells of the battery connected in a series arrangement.
Diffusion-controlled (or diffusion-limited) reactions are reactions in which the reaction rate is equal to the rate of transport of the reactants through the reaction medium (usually a solution). [1] The process of chemical reaction can be considered as involving the diffusion of reactants until they encounter each other in the right ...
Darken’s equations can be applied to almost any scenario involving the diffusion of two different components that have different diffusion coefficients. This holds true except in situations where there is an accompanying volume change in the material because this violates one of Darken’s critical assumptions that atomic volume is constant.