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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. The Gough–Joule effect or the Gow–Joule effect, which is the tendency of elastomers to contract if heated while they are under tension.
The throttling process is a good example of an isoenthalpic process in which significant changes in pressure and temperature can occur to the fluid, and yet the net sum the associated terms in the energy balance is null, thus rendering the transformation isoenthalpic. The lifting of a relief (or safety) valve on a pressure vessel is an example ...
Real gases are non-ideal gases whose molecules occupy space and have interactions; consequently, they do not adhere to the ideal gas law. To understand the behaviour of real gases, the following must be taken into account: compressibility effects; variable specific heat capacity; van der Waals forces; non-equilibrium thermodynamic effects;
The joule (/ dʒ uː l / JOOL, or / dʒ aʊ l / JOWL; symbol: J) is the unit of energy in the International System of Units (SI). [1] In terms of SI base units , one joule corresponds to one kilogram - square metre per square second (1 J = 1 kg⋅m 2 ⋅s −2 ).
Examples are friction on the surface of the system as in Rumford's experiment; shaft work such as in Joule's experiments; stirring of the system by a magnetic paddle inside it, driven by a moving magnetic field from the surroundings; and vibrational action on the system that leaves its eventual volume unchanged, but involves friction within the ...
Adiabatic expansion occurs in the Earth's atmosphere with orographic lifting and lee waves, and this can form pilei or lenticular clouds. Due in part to adiabatic expansion in mountainous areas, snowfall infrequently occurs in some parts of the Sahara desert. [8] Adiabatic expansion does not have to involve a fluid.