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Mercury sulfide, or mercury(II) sulfide is a chemical compound composed of the chemical elements mercury and sulfur. It is represented by the chemical formula HgS. It is virtually insoluble in water.
Mercury(I) sulfide or mercurous sulfide is a hypothetical chemical compound of mercury and sulfur, with elemental formula Hg 2 S.Its existence has been disputed; it may be stable below 0 °C or in suitable environments, but is unstable at room temperature, decomposing into metallic mercury and mercury(II) sulfide (mercuric sulfide, cinnabar).
Mercury(II) sulfide, HgS, adopts the cinnabar structure described, and one additional structure, i.e. it is dimorphous. [16] Cinnabar is the more stable form, and is a structure akin to that of HgO : each Hg center has two short Hg−S bonds (each 2.36 Å ), and four longer Hg···S contacts (with 3.10, 3.10, 3.30 and 3.30 Å separations).
Mercury is a chemical element; ... vermilion is obtained by grinding natural cinnabar or synthetic mercuric sulfide. ... the compound with the formula Hg 2 Cl 2, ...
Retrieved from "https://en.wikipedia.org/w/index.php?title=Mercuric_sulphide&oldid=743223767"This page was last edited on 8 October 2016, at 16:16 (UTC). (UTC).
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Genuine vermilion pigment today comes mostly from China; it is a synthetic mercuric sulfide, labeled on paint tubes as PR-106 (Red Pigment 106). The synthetic pigment is of higher quality than vermilion made from ground cinnabar, which has many impurities. The pigment is very toxic, and should be used with great care. [16]
Metacinnabar is the cubic form of mercury sulfide (HgS). It is the high temperature form and trimorphous with cinnabar (trigonal structure) and the higher temperature hypercinnabar (hexagonal structure).