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Chromium(II) acetate hydrate, also known as chromous acetate, is the coordination compound with the formula Cr 2 (CH 3 CO 2) 4 (H 2 O) 2. This formula is commonly abbreviated Cr 2 (OAc) 4 (H 2 O) 2 . This red-coloured compound features a quadruple bond .
Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals . The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist.
Chromium(II) acetate, Cr 2 (μ-O 2 CCH 3) 4 (H 2 O) 2, was the first chemical compound containing a quadruple bond to be synthesized. It was described in 1844 by E. Peligot, although its distinctive bonding was not recognized for more than a century.
For simple carboxylates, the acetate complexes are illustrative. Most transition metal acetates are mixed ligand complexes. One common example is hydrated nickel acetate, Ni(O 2 CCH 3) 2 (H 2 O) 4, which features intramolecular hydrogen-bonding between the uncoordinated oxygens and the protons of aquo ligands.
The resulting bright blue solution created from dissolving chromium(II) chloride is stable at neutral pH. [21] Some other notable chromium(II) compounds include chromium(II) oxide CrO, and chromium(II) sulfate CrSO 4. Many chromium(II) carboxylates are known. The red chromium(II) acetate (Cr 2 (O 2 CCH 3) 4) is somewhat famous.
Chromium(III) acetate, commonly known as basic chromium acetate, [2] describes a family of salts where the cation has the formula [Cr 3 O(O 2 CCH 3) 6 (OH 2) 3] +. The trichromium cation is encountered with a variety of anions, such as chloride and nitrate. Data in the table above are for the chloride hexahydrate, [Cr 3 O(O 2 CCH 3) 6 (OH 2) 3 ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Chromium acetate may refer to: Chromium(II) acetate; Chromium(III) acetate This page was last edited on 23 February 2021, at 18:52 (UTC). Text is available under the ...