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Lanthanide ions have notable luminescent properties due to their unique 4f orbitals. Laporte forbidden f-f transitions can be activated by excitation of a bound "antenna" ligand. This leads to sharp emission bands throughout the visible, NIR, and IR and relatively long luminescence lifetimes. [85]
The lanthanide ions in these complexes can readily react with oxygen and water, leading to oxidation or hydrolysis, which damages the material’s structure and reduces its efficiency. This makes handling and storage difficult, requiring protective environments like sealed containers or inert gas atmospheres.
The La 3+ metal atoms are surrounded by a 7 coordinate group of O 2− atoms, the oxygen ions are in an octahedral shape around the metal atom and there is one oxygen ion above one of the octahedral faces. [4] On the other hand, at high temperatures lanthanum oxide converts to a C-M 2 O 3 cubic crystal structure.
Lanthanide metals react exothermically with hydrogen to form LnH 2, dihydrides. [1] With the exception of Eu and Yb, which resemble the Ba and Ca hydrides (non-conducting, transparent salt-like compounds),they form black pyrophoric, conducting compounds [6] where the metal sub-lattice is face centred cubic and the H atoms occupy tetrahedral sites. [1]
The lanthanides become harder as the series is traversed: as expected, lanthanum is a soft metal. Lanthanum has a relatively high resistivity of 615 nΩm at room temperature; in comparison, the value for the good conductor aluminium is only 26.50 nΩm. [28] [29] Lanthanum is the least volatile of the lanthanides. [30]
The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), [1] are a set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals.
The fluorescence of lanthanide salts is weak because the energy absorption of the metallic ion is low; hence chelated complexes of lanthanides are most commonly used. [3] The term chelate derives from the Greek word for “claw,” and is applied to name ligands, which attach to a metal ion with two or more donor atoms through dative bonds .
Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl 3, Eu(NO 3) 3 and Eu(CH 3 COO) 3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in ...