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ΔH vap is the molar enthalpy of vaporization of the solvent. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin. This is related to cryoscopy, which determines the same value from the cryoscopic constant (of freezing point ...
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
In thermodynamics, Trouton's rule states that the (molar) entropy of vaporization is almost the same value, about 85–88 J/(K·mol), for various kinds of liquids at their boiling points. [1] The entropy of vaporization is defined as the ratio between the enthalpy of vaporization and the boiling temperature.
A vertical line in the h–s chart represents an isentropic process. The process 3–4 in a Rankine cycle is isentropic when the steam turbine is said to be an ideal one. So the expansion process in a turbine can be easily calculated using the h–s chart when the process is considered to be ideal (which is the case normally when calculating ...
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
In thermodynamics, the entropy of vaporization is the increase in entropy upon vaporization of a liquid.This is always positive, since the degree of disorder increases in the transition from a liquid in a relatively small volume to a vapor or gas occupying a much larger space.
ΔH for a phase transition is a weak function of temperature. In some texts, the heats of phase transitions are called latent heats (for example, latent heat of fusion). Molar enthalpy of zinc above 298.15 K and at 1 atm pressure, showing discontinuities at the melting and boiling points. The ΔH°m of zinc is 7323 J/mol, and the ΔH°v is 115 ...
Boiling-point diagram. The preceding equilibrium equations are typically applied for each phase (liquid or vapor) individually, but the result can be plotted in a single diagram. In a binary boiling-point diagram, temperature (T ) (or sometimes pressure) is graphed vs. x 1. At any given temperature (or pressure) where both phases are present ...