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Phosgenite is a rare mineral consisting of lead carbonate chloride, (PbCl) 2 CO 3. The tetragonal crystals are prismatic or tabular in habit: they are usually colorless and transparent, and have a brilliant adamantine lustre. Sometimes the crystals have a curious helical twist about the tetrad or principal axis. The hardness is 3 and the ...
x PbCl 2(l) + BaTiO 3(s) → Ba 1−x Pb x TiO 3 + x BaCl 2; PbCl 2 is used in production of infrared transmitting glass, [14] and ornamental glass called aurene glass. Aurene glass has an iridescent surface formed by spraying with PbCl 2 and reheating under controlled conditions. Stannous chloride (SnCl 2) is used for the same purpose. [15]
PbCl 2, PbBr 2 and PbI 2 are commonly used to produce donor centers. Other n-type doping agents such as Bi 2 Te 3 , TaTe 2 , MnTe 2 , will substitute for Pb and create uncharged vacant Pb-sites. These vacant sites are subsequently filled by atoms from the lead excess and the valence electrons of these vacant atoms will diffuse through crystal.
It is then converted to the ammonium salt (NH 4) 2 PbCl 6 by adding ammonium chloride (NH 4 Cl). Finally, the solution is treated with concentrated sulfuric acid H 2 SO 4, to separate out lead tetrachloride. This series of reactions is conducted at 0 °C. The following equations illustrate the reaction: PbCl 2 + 2HCl + Cl 2 → H 2 PbCl 6
It dissolves in nitric acid with the evolution of nitric oxide gas to form dissolved Pb(NO 3) 2. 3 Pb + 8 H + + 8 NO − 3 → 3 Pb 2+ + 6 NO − 3 + 2 NO + 4 H 2 O. When heated with nitrates of alkali metals, metallic lead oxidizes to form PbO (also known as litharge), leaving the corresponding alkali nitrite. PbO is representative of lead's ...
In statistical process control (SPC), the ¯ and R chart is a type of scheme, popularly known as control chart, used to monitor the mean and range of a normally distributed variables simultaneously, when samples are collected at regular intervals from a business or industrial process. [1]
Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
Addition of hydrogen sulfide or sulfide salts to a solution containing a lead salt, such as PbCl 2, gives a black precipitate of lead sulfide. Pb 2+ + H 2 S → PbS↓ + 2 H + This reaction is used in qualitative inorganic analysis. The presence of hydrogen sulfide or sulfide ions may be tested using "lead acetate paper."