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Acrylic yarn dyed with basic dyes. Acrylic fibers are synthetic fibers made from a polymer (polyacrylonitrile) with an average molecular weight of ~100,000, about 1900 monomer units. For a fiber to be called "acrylic" in the US, the polymer must contain at least 85% acrylonitrile monomer. Typical comonomers are vinyl acetate or methyl acrylate.
It was made into the spun fiber at DuPont in 1942 and marketed under the name of Orlon. Acrylonitrile is commonly employed as a comonomer with styrene, e.g. acrylonitrile, styrene and acrylate plastics. Labelling of items of clothing with acrylic (see acrylic fiber) means the polymer consists of at least 85% acrylonitrile as the monomer. A ...
Modacrylic fibers are modified acrylic fibers made from acrylonitriles, but larger amounts of other polymers are added to make the copolymers. The modacrylic fibers are produced by polymerizing the components, dissolving the copolymer in acetone, pumping the solution into the column of warm air (dry-spun), and stretching while hot. [3]
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In general, synthetic fibers are created by extruding fiber-forming materials through spinnerets, forming a fiber. These are called synthetic or artificial fibers. The word polymer comes from a Greek prefix "poly" which means "many" and suffix "mer" which means "single units". (Note: each single unit of a polymer is called a monomer).
Rayon is a classified as a semi-synthetic fiber, made with natural polymers. Monomers are the building blocks of polymers. Polymers in fibers are of two types: additive or condensation. Natural fibers, such as cotton and wool, have a condensation polymer type, whereas synthetic fibers can have either an additive or a condensation polymer type.