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Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite forms by a eutectoid reaction as austenite cools below 723 °C (1,333 °F) (the eutectoid temperature).
A very rapid quench is essential to create martensite. For a eutectoid carbon steel of thin section, if the quench starting at 750 °C and ending at 450 °C takes place in 0.7 seconds (a rate of 430 °C/s) no pearlite will form, and the steel will be martensitic with small amounts of retained austenite. [2]
Carbon agglomerates into small roughly spherical aggregates of graphite, leaving a matrix of ferrite or pearlite according to the exact heat treatment used. Three basic types of malleable iron are recognized within the casting industry: blackheart, whiteheart, and pearlitic. [1]
They are often observed in cases where a phase transition front moves quickly, leaving behind two solid products, as in rapid cooling of eutectic (such as solder) or eutectoid (such as pearlite) systems. Such conditions force phases of different composition to form but allow little time for diffusion to produce those phases' equilibrium ...
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The morphology of cementite plays a critical role in the kinetics of phase transformations in steel. The coiling temperature and cooling rate significantly affect cementite formation. At lower coiling temperatures, cementite forms fine pearlitic colonies, whereas at higher temperatures, it precipitates as coarse particles at grain boundaries.