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The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell , giving it the same electronic configuration as a noble gas .
Thus both hydrogen atoms have an electron count of one. The oxygen atom has 6 valence electrons. The total electron count is 8, which agrees with the octet rule. This figure of the water molecule shows how the electrons are distributed with the ionic counting method. The red ones are the oxygen electrons, and the blue ones are electrons from ...
Main-group atoms generally obey the octet rule, while transition metals generally obey the 18-electron rule. The noble gases (He, Ne, Ar, Kr, Xe, Rn) are less reactive than other elements because they already have a noble gas configuration. Oganesson is predicted to be more reactive due to relativistic effects for heavy atoms.
They therefore do not follow the octet rule, but rather a duplet rule. Chemically, helium behaves like a noble gas , and thus is taken to be part of the group 18 elements . However, in terms of its nuclear structure it belongs to the s-block , and is therefore sometimes classified as a group 2 element , or simultaneously both 2 and 18.
The 18-electron rule is a chemical rule of thumb used primarily for predicting and rationalizing formulas for stable transition metal complexes, especially organometallic compounds. [1] The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five ( n −1)d orbitals, one n s orbital ...
In the diagram of methane shown here, the carbon atom has a valence of four and is, therefore, surrounded by eight electrons (the octet rule), four from the carbon itself and four from the hydrogens bonded to it. Each hydrogen has a valence of one and is surrounded by two electrons (a duet rule) – its own one electron plus one from the carbon.
A trick is to count up valence electrons, then count up the number of electrons needed to complete the octet rule (or with hydrogen just 2 electrons), then take the difference of these two numbers. The answer is the number of electrons that make up the bonds. The rest of the electrons just go to fill all the other atoms' octets.
In chemistry, electron deficiency (and electron-deficient) is jargon that is used in two contexts: chemical species that violate the octet rule because they have too few valence electrons and species that happen to follow the octet rule but have electron-acceptor properties, forming donor-acceptor charge-transfer salts.