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According to experimental evidence from microwave spectroscopy, ozone is a bent molecule, with C 2v symmetry (similar to the water molecule). [31] The O–O distances are 127.2 pm (1.272 Å). The O–O–O angle is 116.78°. [32] The central atom is sp² hybridized with one lone pair. Ozone is a polar molecule with a dipole moment of 0.53 D. [33]
Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone.
Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O 2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O 2 to create ozone, O 3. The ozone molecule is unstable (although, in the stratosphere, long-lived ...
Ozone cycle illustrated over image by NASA astronaut Scott Kelly. Ozone is a ubiquitous yet highly reactive molecule in the atmosphere. Such a highly reactive oxidizer would normally be dangerous to life but ozone's concentration at sea level is usually not high enough to be toxic.
ozone photodissociation: O 3 + ℎν (240–310 nm) → O 2 + O. The atomic oxygen produced may react with another oxygen molecule to reform ozone via the ozone creation reaction (reaction 2 above). These two reactions thus form the ozone–oxygen cycle, wherein the chemical energy released by ozone creation becomes molecular kinetic energy.
These ozone molecules absorb UVB light, following which ozone splits into a molecule of O 2 and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process that terminates when an oxygen atom recombines with an ozone molecule to make two O 2 molecules. It is worth noting that ozone is ...
Tetraoxygen was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of liquid oxygen to obey Curie's law. [1] Though not entirely inaccurate, computer simulations indicate that although there are no stable O 4 molecules in liquid oxygen, O 2 molecules do tend to associate in pairs with antiparallel spins, forming transient O 4 units. [2]
2 combines with atomic oxygen made by the splitting of O 2 by ultraviolet (UV) radiation. [22] Since ozone absorbs strongly in the UV region of the spectrum, the ozone layer of the upper atmosphere functions as a protective radiation shield for the planet. [22] Near the Earth's surface, it is a pollutant formed as a by-product of automobile ...