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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The two most prevalent ions in seawater are chloride and sodium. Together, they make up around 85 per cent of all dissolved ions in the ocean. Magnesium and sulfate ions make up most of the rest. Salinity varies with temperature, evaporation, and precipitation. It is generally low at the equator and poles, and high at mid-latitudes. [12]
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
For his 1934 paper, Alfred Redfield analyzed nitrate and phosphate data for the Atlantic, Indian, Pacific oceans and Barents Sea. [1] As a Harvard physiologist, Redfield participated in several voyages on board the research vessel Atlantis, analyzing data for C, N, and P content in marine plankton, and referenced data collected by other researchers as early as 1898.
Conservative temperature is defined to be directly proportional to potential enthalpy. It is rescaled to have the same units as the in-situ temperature: = where = 3989.24495292815 J kg −1 K −1 is a reference value of the specific heat capacity, chosen to be as close as possible to the spatial average of the heat capacity over the entire ocean surface.
Temperature and salinity combine to determine the potential density of seawater; contours of constant potential density are often shown in T-S diagrams. Each contour is known as an isopycnal, or a region of constant density. These isopycnals appear curved because of the nonlinearity of the equation of state of seawater.
Seawater, or sea water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately 35 grams (1.2 oz) of dissolved salts (predominantly sodium ( Na +
[2] [3] [4] Pelagic life decreases as depth increases. The pelagic zone contrasts with the benthic and demersal zones at the bottom of the sea. The benthic zone is the ecological region at the very bottom, including the sediment surface and some subsurface layers. Marine organisms such as clams and crabs living in this zone are called benthos ...