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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
This process is known as thermohaline circulation. In the Earth's polar regions ocean water gets very cold, forming sea ice. As a consequence the surrounding seawater gets saltier, because when sea ice forms, the salt is left behind. As the seawater gets saltier, its density increases, and it starts to sink.
A change in pH by 0.1 represents a 26% increase in hydrogen ion concentration in the world's oceans (the pH scale is logarithmic, so a change of one in pH units is equivalent to a tenfold change in hydrogen ion concentration). Sea-surface pH and carbonate saturation states vary depending on ocean depth and location.
Relationship of phosphate to nitrate uptake for photosynthesis in various regions of the ocean. Note that nitrate is more often limiting than phosphate. The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon, nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans.
The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at 4 °C (39 °F)) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases.
He found that in seawater the major ions were in a fixed ratio, confirming the hypothesis of Johan Georg Forchhammer, that is now known as the Principle of Constant Proportions. However, there was one exception. Dittmar found that the concentration of calcium was slightly greater in the deep ocean, and named this increase alkalinity. [citation ...
S in seawater, limiting the utility of the otherwise more straightforward free scale. Another scale, known as the seawater scale, often denoted pH SWS, takes account of a further protonation relationship between hydrogen ions and fluoride ions, H + + F − ⇌ HF. Resulting in the following expression for [H +] SWS: [H +] SWS = [H +] F + [HSO ...
The decreasing saturation of seawater with respect to calcium carbonate, associated with ocean acidification, a result of increased carbon dioxide (CO 2) absorption by the oceans, poses a significant threat to marine calcifiers. As CO 2 concentrations in seawater rise, a decrease in pH and a reduction in carbonate ion concentrations in seawater ...