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Instead, numerical methods (including finite elements and lattice Boltzmann methods) are generally used to find approximate solutions to the various forms of the Boltzmann equation. Example applications range from hypersonic aerodynamics in rarefied gas flows [16] [17] to plasma flows. [18]
Boltzmann's equation—carved on his gravestone. [1]In statistical mechanics, Boltzmann's equation (also known as the Boltzmann–Planck equation) is a probability equation relating the entropy, also written as , of an ideal gas to the multiplicity (commonly denoted as or ), the number of real microstates corresponding to the gas's macrostate:
A different interpretation of the lattice Boltzmann equation is that of a discrete-velocity Boltzmann equation. The numerical methods of solution of the system of partial differential equations then give rise to a discrete map, which can be interpreted as the propagation and collision of fictitious particles.
The kinetic equation and in particular Boltzmann's molecular chaos assumption inspired a whole family of Boltzmann equations that are still used today to model the motions of particles, such as the electrons in a semiconductor. In many cases the molecular chaos assumption is highly accurate, and the ability to discard complex correlations ...
Ludwig Boltzmann defined entropy as a measure of the number of possible microscopic states (microstates) of a system in thermodynamic equilibrium, consistent with its macroscopic thermodynamic properties, which constitute the macrostate of the system. A useful illustration is the example of a sample of gas contained in a container.
The Lattice Boltzmann methods for solids (LBMS) are a set of methods for solving partial differential equations (PDE) in solid mechanics. The methods use a discretization of the Boltzmann equation(BM), and their use is known as the lattice Boltzmann methods for solids. LBMS methods are categorized by their reliance on: Vectorial distributions [1]
Boltzmann's equation = is the realization that the entropy is proportional to with the constant of proportionality being the Boltzmann constant. Using the ideal gas equation of state ( PV = NkT ), It follows immediately that β = 1 / k T {\displaystyle \beta =1/kT} and α = − μ / k T {\displaystyle \alpha =-\mu /kT} so that the ...
The Boltzmann–Matano method is used to convert the partial differential equation resulting from Fick's law of diffusion into a more easily solved ordinary differential equation, which can then be applied to calculate the diffusion coefficient as a function of concentration.