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Crystal of potassium alum, KAl(SO 4) 2 ·12H 2 O. An alum (/ ˈ æ l ə m /) is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula X Al(SO 4) 2 ·12 H 2 O, such that X is a monovalent cation such as potassium or ammonium. [1] By itself, "alum" often refers to potassium alum, with the ...
Ammonium aluminium sulfate, also known as ammonium alum or just alum (though there are many different substances also called "alum"), is a white crystalline double sulfate usually encountered as the dodecahydrate, formula (NH 4)Al(SO 4) 2 ·12H 2 O. It is used in small amounts in a variety of niche applications.
Alum-(K) is a hydrous potassium aluminium sulfate mineral with formula KAl(SO 4) 2 ·12(H 2 O). It is the mineral form of potassium alum and is referred to as potassium alum in older sources. It is a member of the alum group. [2] It occurs as colorless to white, soft isometric crystals and efflorescence coatings. [3]
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
The ancients are known to have used alum as a dyeing mordant and for city defense. [75] After the Crusades, alum, an indispensable good in the European fabric industry, [76] was a subject of international commerce; [77] it was imported to Europe from the eastern Mediterranean until the mid-15th century. [78] The nature of alum remained unknown.
1 (rh.) 3 (hex.) 6 nearest neighbours at 234 K and 1 atm (it is liquid at room temperature and thus has no crystal structure at ambient conditions!) Identical symmetry to the β-Po structure, distinguished based on details about the basis vectors of its unit cell.
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Historically, crystal shape was defined by measuring the angles between crystal faces with a goniometer. Whereas crystals of Fe(acac) 3 are deep red and crystals of Al(acac) 3 are colorless, a solid solution of the two, i.e. Fe 1−x Al x (acac) 3 will be deep or pale pink depending on the Fe/Al ratio, x.