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Saturated fatty acids 16 and 18 carbons in length are the dominant types in the epidermis, [39] [40] while unsaturated fatty acids and saturated fatty acids of various other lengths are also present. [ 39 ] [ 40 ] The relative abundance of the different fatty acids in the epidermis is dependent on the body site the skin is covering. [ 40 ]
Tridecanoic acid CH 3 (CH 2) 11 COOH C13:0 Myristic acid: Tetradecanoic acid CH 3 (CH 2) 12 COOH C14:0 Pentadecylic acid: Pentadecanoic acid CH 3 (CH 2) 13 COOH C15:0 Palmitic acid: Hexadecanoic acid CH 3 (CH 2) 14 COOH C16:0 Margaric acid: Heptadecanoic acid CH 3 (CH 2) 15 COOH C17:0 Stearic acid: Octadecanoic acid CH 3 (CH 2) 16 COOH C18:0 ...
Cervonic acid (or docosahexaenoic acid) has 22 carbons, is found in fish oil, is a 4,7,10,13,16,19-hexa unsaturated fatty acid. In the human body its generation depends on consumption of omega 3 essential fatty acids (e.g., ALA or EPA), but the conversion process is inefficient. [ 22 ]
An omega−3 fatty acid is a fatty acid with multiple double bonds, where the first double bond is between the third and fourth carbon atoms from the end of the carbon atom chain. "Short-chain" omega−3 fatty acids have a chain of 18 carbon atoms or less, while "long-chain" omega−3 fatty acids have a chain of 20 or more.
Short-chain fatty acids (SCFAs) are fatty acids of two to six carbon atoms. [1] The SCFAs' lower limit is interpreted differently, either with one, two, three or four carbon atoms. [ citation needed ] Derived from intestinal microbial fermentation of indigestible foods, SCFAs in human gut are acetic, propionic and butyric acid.
Omega-3 fatty acids have a double bond three carbons away from the methyl carbon, whereas omega-6 fatty acids have a double bond six carbons away from the methyl carbon. The illustration below shows the omega-6 fatty acid, linoleic acid. Polyunsaturated fatty acids can be classified in various groups by their chemical structure:
A saturated fat is a type of fat in which the fatty acid chains have all single bonds between the carbon atoms. A fat known as a glyceride is made of two kinds of smaller molecules: a short glycerol backbone, and fatty acids that each contain a long linear or branched chain of carbon (C) atoms.
Structure of a triglyceride containing myristic, palmitic, and oleic acid. Butterfat is mainly composed of triglycerides. Each triglyceride contains three fatty acids. Butterfat triglycerides contain the following amounts of fatty acids (by mass fraction): [1] [2] [3]