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Bromine monofluoride is a quite unstable interhalogen compound with the chemical formula BrF. It can be produced through the reaction of bromine trifluoride (or bromine pentafluoride) and bromine. Due to its lability, the compound can be detected but not isolated: [2] BrF 3 + Br 2 → 3 BrF BrF 5 + 2 Br 2 → 5 BrF Br 2(l) + F 2(g) → 2 BrF (g)
Carbon monofluoride (CF, CF x, or (CF) x), also called polycarbon monofluoride; Chlorine monofluoride, a volatile interhalogen compound with formula ClF; Iodine monofluoride, a chocolate-brown solid compound with formula IF; Hydrogen fluoride, a liquid or gas with boiling point at about 20 °C, HF; Nitrogen monofluoride, a metastable compound ...
Chlorine monofluoride (ClF) is the lightest interhalogen compound. ClF is a colorless gas with a normal boiling point of −100 °C. Bromine monofluoride (BrF) has not been obtained as a pure compound — it dissociates into the trifluoride and free bromine. It is created according to the following equation: Br 2 (l) + F 2 (g) → 2 BrF(g)
The F 2 molecule is commonly described as having exactly one bond (in other words, a bond order of 1) provided by one p electron per atom, as are other halogen X 2 molecules. However, the heavier halogens' p electron orbitals partly mix with those of d orbitals, which results in an increased effective bond order; for example, chlorine has a ...
Bromine fluoride may refer to several compounds with the elements bromine and fluorine: Bromine monofluoride, BrF;
Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V ...
Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.
A fairly well-defined reaction front can often be observed in thin sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and the microstructure of concrete are modified. These changes may vary in type or severity but commonly include: Extensive cracking; Expansion