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Sodium silicate is also the technical and common name for a mixture of such compounds, chiefly the metasilicate, also called waterglass, water glass, or liquid glass. The product has a wide variety of uses, including the formulation of cements , coatings, passive fire protection , textile and lumber processing, manufacture of refractory ...
The subunits of colloidal silica particles are typically in the range of 1 to 5 nm. Whether or not these subunits are joined depends on the conditions of polymerization. Initial acidification of a water-glass (sodium silicate) solution yields Si(OH) 4. If the pH is reduced below 7 or if salt is added, then the units tend to fuse together in chains.
Silicates with alkali cations and small or chain-like anions, such as sodium ortho-and metasilicate, are fairly soluble in water. They form several solid hydrates when crystallized from solution. Soluble sodium silicates and mixtures thereof, known as waterglass are important industrial and household chemicals. Silicates of non-alkali cations ...
Sulfuric acid and sodium silicate solutions are added simultaneously with agitation to water. Precipitation is carried out under acidic or basic conditions. The choice of agitation , duration of precipitation, the addition rate of reactants, their temperature and concentration and pH can vary the properties of the resulting silica.
3, which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations Na + and the polymeric metasilicate anions [– SiO 2− 3 –] n. It is a colorless crystalline hygroscopic and deliquescent solid, soluble in water (giving an alkaline solution) but not in alcohols. [1]
An aqueous solution of sodium silicate is acidified to produce a gelatinous precipitate that is washed, then dehydrated to produce colorless silica gel. [6] When a visible indication of the moisture content of the silica gel is required, ammonium tetrachlorocobaltate(II) (NH 4) 2 [CoCl 4] or cobalt(II) chloride CoCl 2 is added. [6]