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Boron trioxide or diboron trioxide is the oxide of boron with the formula B 2 O 3. It is a colorless transparent solid, almost always glassy (amorphous), which can be crystallized only with great difficulty.
Download as PDF; Printable version; In other projects ... Boron oxide may refer to one of several oxides of boron: Boron trioxide (B 2 O 3, diboron trioxide), the ...
Boron carbide – B 4 C [143] Boron nitride – BN [144] Boron suboxide – B 6 O [145] Boron tribromide – BBr 3 [146] Boron trichloride – BCl 3 [147] Boron trifluoride – BF 3 [148] Boron triiodide –BI 3 [149] Boron oxide – B 2 O 3 [150] Boroxine – B 3 H 3 O 3 [151] Decaborane – B 10 H 14 [152] Diborane – B 2 H 6 [153] Diboron ...
Often the boron in borides has fractional oxidation states, such as −1/3 in calcium hexaboride (CaB 6). From the structural perspective, the most distinctive chemical compounds of boron are the hydrides. Included in this series are the cluster compounds dodecaborate (B 12 H 2− 12), decaborane (B 10 H 14), and the carboranes such as C 2 B 10 ...
Guitar slide made of borosilicate glass. Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10 −6 K −1 at 20 °C), making them more resistant to thermal shock than any other common glass.
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]
It is not well known and was discovered accidentally by an attempt trying to make boron triacetate in the 1950s. It was made by reacting boric acid and acetic anhydride around 75 °C (167 °F) under nitrogen which created tetraacetyl diborate and acetic acid. It crystallized as a colorless solid. [1]
It is formed by the reaction of boric acid and ethanol in the presence of acid catalyst, where it forms according to the equilibrium reaction: B(OH) 3 + 3 C 2 H 5 OH ⇌ (C 2 H 5 O) 3 B + 3 H 2 O. In order to increase the rate of forward reaction, the formed water must be removed from reaction media by either azeotropic distillation or adsorption.