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  2. Ives–Stilwell experiment - Wikipedia

    en.wikipedia.org/wiki/Ives–Stilwell_experiment

    A considerably higher precision has been achieved in modern variations of Ives–Stilwell experiments. In heavy-ion storage rings, as the TSR at the MPIK or ESR at the GSI Helmholtz Centre for Heavy Ion Research, the Doppler shift of lithium ions traveling at high speed [21] is evaluated by using saturated spectroscopy or optical–optical ...

  3. Stability constants of complexes - Wikipedia

    en.wikipedia.org/wiki/Stability_constants_of...

    The chelate effect increases as the number of chelate rings increases. For example, the complex [Ni(dien) 2)] 2+ is more stable than the complex [Ni(en) 3)] 2+; both complexes are octahedral with six nitrogen atoms around the nickel ion, but dien (diethylenetriamine, 1,4,7-triazaheptane) is a tridentate ligand and en is bidentate. The number of ...

  4. Chemical stability - Wikipedia

    en.wikipedia.org/wiki/Chemical_stability

    In chemistry, chemical stability is the thermodynamic stability of a chemical system, in particular a chemical compound or a polymer. [1]Chemical stability may also refer to the shelf-life of a particular chemical compound; that is the duration of time before it begins to degrade in response to environmental factors.

  5. Equilibrium chemistry - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_chemistry

    When hard water is passed through the resin, the divalent ions of magnesium and calcium displace the sodium ions and are retained on the resin, R. RNa + M 2+ ⇌ RM + + Na + The water coming out of the column is relatively rich in sodium ions [note 8] and poor in calcium and magnesium which are retained on the column. The column is regenerated ...

  6. Chemical ionization - Wikipedia

    en.wikipedia.org/wiki/Chemical_ionization

    Electrons entering the source will mainly ionize the reagent gas because it is in large excess compared to the analyte. The primary reagent ions then undergo secondary ion/molecule reactions (as below) to produce more stable reagent ions which ultimately collide and react with the lower concentration analyte molecules to form product ions.

  7. Rutherford scattering experiments - Wikipedia

    en.wikipedia.org/wiki/Rutherford_scattering...

    The prevailing model of atomic structure before Rutherford's experiments was devised by J. J. Thomson. [1]: 123 Thomson had discovered the electron through his work on cathode rays [2] and proposed that they existed within atoms, and an electric current is electrons hopping from one atom to an adjacent one in a series.

  8. Carbonium ion - Wikipedia

    en.wikipedia.org/wiki/Carbonium_ion

    In chemistry, a carbonium ion is a cation that has a pentacoordinated carbon atom. [2] They are a type of carbocation. In older literature, the name "carbonium ion" was used for what is today called carbenium. Carbonium ions charge is delocalized in three-center, two-electron bonds. The more stable members are often bi- or polycyclic. [3]

  9. Ionization - Wikipedia

    en.wikipedia.org/wiki/Ionization

    Positively charged ions are produced by transferring an amount of energy to a bound electron in a collision with charged particles (e.g. ions, electrons or positrons) or with photons. The threshold amount of the required energy is known as ionization potential .