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Peter William Atkins FRSC (born 10 August 1940) is an English chemist and a Fellow of Lincoln College at the University of Oxford.He retired in 2007. He is a prolific writer of popular chemistry textbooks, including Physical Chemistry, Inorganic Chemistry, and Molecular Quantum Mechanics.
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.
Description: A classic general textbook for an undergraduate course in physical chemistry Importance: This book is not only a good introduction to the subject, it was very different from earlier texts and altered the way physical chemistry was taught. The first edition was very widely used where English is the language of instruction.
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In physical chemistry, the McConnell equation gives the probability of an unpaired electron in an in aromatic radical compound (such as benzene radical anion) being on a particular atom. It relates this probability, known as the "spin density", to its proportional dependence on the hyperfine splitting constant .
While at the interface of physics and chemistry, chemical physics is distinct from physical chemistry as it focuses more on using physical theories to understand and explain chemical phenomena at the microscopic level, such as quantum mechanics, statistical mechanics, and molecular dynamics. Meanwhile, physical chemistry uses a broader range of ...
where G is the Gibbs free energy. The equation of the Gibbs Adsorption Isotherm can be derived from the “particularization to the thermodynamics of the Euler theorem on homogeneous first-order forms.” [ 4 ] The Gibbs free energy of each phase α , phase β , and the surface phase can be represented by the equation: