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Diagram of an electrode used in the field. The copper–copper (II) sulfate electrode is a reference electrode of the first kind, [1] based on the redox reaction with participation of the metal (copper) and its salt, copper (II) sulfate. It is used for measuring electrode potential and is the most commonly used reference electrode for testing ...
The Daniell cell is a type of electrochemical cell invented in 1836 by John Frederic Daniell, a British chemist and meteorologist, and consists of a copper pot filled with a copper (II) sulfate solution, in which is immersed an unglazed earthenware container filled with sulfuric acid and a zinc electrode. He was searching for a way to eliminate ...
A reference electrode is an electrode that has a stable and well-known electrode potential. The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with ...
A galvanic cell consists of two half-cells, such that the electrode of one half-cell is composed of metal A, and the electrode of the other half-cell is composed of metal B; the redox reactions for the two separate half-cells are thus: A n+ + ne − ⇌ A B m+ + me − ⇌ B. The overall balanced reaction is: m A + n B m+ ⇌ n B + m A n+
The data below tabulates standard electrode potentials (E °), in volts relative to the standard hydrogen electrode (SHE), at: Absolute partial pressure 101.325 kPa (1.00000 atm; 1.01325 bar) for each gaseous reagent — the convention in most literature data but not the current standard state (100 kPa). Variations from these ideal conditions ...
Electrochemical cell. A demonstration electrochemical cell setup resembling the Daniell cell. The two half-cells are linked by a salt bridge carrying ions between them. Electrons flow in the external circuit. An electrochemical cell is a device that generates electrical energy from chemical reactions. Electrical energy can also be applied to ...
Half-reaction. In chemistry, a half reaction (or half-cell reaction) is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Often, the concept of half reactions is used to describe what occurs ...
Half-cell. In electrochemistry, a half-cell is a structure that contains a conductive electrode and a surrounding conductive electrolyte separated by a naturally occurring Helmholtz double layer. Chemical reactions within this layer momentarily pump electric charges between the electrode and the electrolyte, resulting in a potential difference ...