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Chromium(II) acetate hydrate, also known as chromous acetate, is the coordination compound with the formula Cr 2 (CH 3 CO 2) 4 (H 2 O) 2. This formula is commonly abbreviated Cr 2 (OAc) 4 (H 2 O) 2 . This red-coloured compound features a quadruple bond .
Chromium(II) chloride describes inorganic compounds with the formula Cr Cl 2 (H 2 O) n. The anhydrous solid is white when pure, however commercial samples are often grey or green; it is hygroscopic and readily dissolves in water to give bright blue air-sensitive solutions of the tetrahydrate Cr(H 2 O) 4 Cl 2 .
It is a name reaction, named for Kazuhiko Takai, who first reported it in 1986. [1] In the original reaction, the organochromium species is generated from iodoform or bromoform and an excess of chromium(II) chloride and the product is a vinyl halide. One main advantage of this reaction is the E-configuration of the double bond that is formed.
The structure of chromocene has been verified by X-ray crystallography.The average Cr–C bond length is 215.1(13) pm. [6] Each molecule contains an atom of chromium bound between two planar systems of five carbon atoms known as cyclopentadienyl (Cp) rings in a sandwich arrangement, which is the reason its formula is often abbreviated as Cp 2 Cr.
Chromium(II) carbide is a ceramic ... Synthesis of chromium carbide can be achieved through mechanical alloying. ... The exothermic reaction is initiated, and the ...
The Nozaki–Hiyama–Kishi reaction is a nickel/chromium coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. [1] In their original 1977 publication, Tamejiro Hiyama and Hitoshi Nozaki [2] reported on a chromium(II) salt solution prepared by reduction of chromic chloride by lithium aluminium hydride to which was added benzaldehyde and allyl ...
The Pourbaix diagram for chromium in pure water, perchloric acid, or sodium hydroxide [1] [2] Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals. The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium ...
According to Nikumbh et al., CrC 2 O 4 ·2H 2 O can be prepared from chromium(II) sulfate pentahydrate by reaction with a mixture of sodium oxalate and oxalic acid in degassed aqueous solution, forming a light green crystalline product, which has been characterized by combustion elemental analysis, infrared spectroscopy, thermogravimetric analysis and powder X-ray diffraction. [1]