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The oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an aldehyde hydrate (gem-diol, R-CH(OH) 2) by reaction with water. Thus, the oxidation of a primary alcohol at the aldehyde level without further oxidation to the carboxylic acid is possible by performing the reaction ...
"Glacial acetic acid" is a name for water-free acetic acid. Similar to the German name "Eisessig" ("ice vinegar"), the name comes from the solid ice-like crystals that form with agitation, slightly below room temperature at 16.6 °C (61.9 °F). Acetic acid can never be truly water-free in an atmosphere that contains water, so the presence of 0. ...
A. aceti is a unique microorganism because of its ability to survive in high concentrations of acetic acid. [9] This microbe utilizes a two-step oxidation of ethanol to acetate. Ethanol is oxidized by membrane-bound proteins called pyrroloquinoline quinone-dependent alcohol dehydrogenase (PQQ- dependent ADH) to produce acetyl aldehyde.
Under alcoholic conditions, the citric acid cycle is stalled by the oversupply of NADH derived from ethanol oxidation. The resulting backup of acetate shifts the reaction equilibrium for acetaldehyde dehydrogenase back towards acetaldehyde. Acetaldehyde subsequently accumulates and begins to form covalent bonds with cellular macromolecules ...
Acetic acid bacteria (AAB) are a group of Gram-negative bacteria which oxidize sugars or ethanol and produce acetic acid during fermentation. [1] The acetic acid bacteria consist of 10 genera in the family Acetobacteraceae. [1] Several species of acetic acid bacteria are used in industry for production of certain foods and chemicals. [1]
Acetobacter is a genus of acetic acid bacteria.Acetic acid bacteria are characterized by the ability to convert ethanol to acetic acid in the presence of oxygen.Of these, the genus Acetobacter is distinguished by the ability to oxidize lactate and acetate into carbon dioxide and water. [2]
The oxidation product of ethanol, acetic acid, is a nutrient for humans, being a precursor to acetyl CoA, where the acetyl group can be spent as energy or used for biosynthesis.
Acetogenesis is a process through which acetyl-CoA [1] or acetic acid is produced by anaerobic bacteria through the reduction of CO 2 via the Wood–Ljungdahl pathway.Other microbial processes that produce acetic acid (like certain types of fermentation or the oxidative breakdown of carbohydrates or ethanol by acetic acid bacteria) are not considered acetogenesis.