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2 NH 3 + H 2 SO 4 → (NH 4) 2 SO 4. A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C. Concentrated sulfuric acid is added to keep the solution acidic, and to retain its level of free acid.
Ammonium sulfite can be prepared by the reaction of ammonia with sulfur dioxide in aqueous solution: 2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process.
Ammonium sulfate is an inorganic salt with a high solubility that disassociates into ammonium (NH + 4) and sulfate (SO 2− 4) in aqueous solutions. [1] Ammonium sulfate is especially useful as a precipitant because it is highly soluble, stabilizes protein structure, has a relatively low density, is readily available, and is relatively inexpensive.
It can also be obtained by hydrolysis of sulfamic acid in aqueous solution, which produces the salt in high purity: H 3 NSO 3 + H 2 O → (NH 4)HSO 4. It also arises by the thermal decomposition of ammonium sulfate: (NH 4) 2 SO 4 → (NH 4)HSO 4 + NH 3
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O. Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate. It is a common laboratory reagent because it is readily crystallized, and crystals resist oxidation ...
Ammonium sulfate, [NH 4] 2 SO 4, a side-product insoluble in liquid ammonia, is removed by filtration; the liquid ammonia is evaporated to give the desired product. [4] The net reaction is: 2 NO − 2 + 4 SO 2 + 6 H 2 O + 6 NH 3 → 4 SO 2− 4 + 6 [NH 4] + + 2 NH 2 OH. A base then frees the hydroxylamine from the salt:
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It is the salt derived from the ammonium cation and the hydrosulfide anion.The salt exists as colourless, water-soluble, micaceous crystals. On Earth the compound is encountered mainly as a solution, not as the solid, but [NH 4]SH ice is believed to be a substantial component of the cloud decks of the gas-giant planets Jupiter and Saturn, with sulfur produced by its photolysis responsible for ...