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In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma or pi bond contained within the parent molecule but not conjugated with the reaction centre.
Wiley-Interscience, 3rd edition, 1999, ISBN 0-471-16019-9; Wiley-Interscience, 4th edition, 2007, ISBN 0-471-69754-0; Wiley-Interscience, 5th edition, 2014, ISBN 9781118057483; Description: A comprehensive reference for the usage of protecting groups in organic synthesis. Importance: A reference publication.
Iodosobenzene is prepared from iodobenzene. [3] It is prepared by first oxidizing iodobenzene by peracetic acid.Hydrolysis of resulting diacetate affords "PhIO": [4] C 6 H 5 I + CH 3 CO 3 H + CH 3 CO 2 H → C 6 H 5 I(O 2 CCH 3) 2 + H 2 O
In one important reaction type, a main group organometallic compound of the type R-M (where R = organic group, M = main group centre metal atom) reacts with an organic halide of the type R'-X with formation of a new carbon-carbon bond in the product R-R'. The most common type of coupling reaction is the cross coupling reaction.
The suffix-oate is the IUPAC nomenclature used in organic chemistry to form names of compounds formed with ester. They are of two types: They are of two types: Formed by replacing the hydrogen atom in the –COOH by some other radical , usually an alkyl or aryl radical forming an ester .
In chemistry, an acyl group is a moiety derived by the removal of one or more hydroxyl groups from an oxoacid, [1] including inorganic acids. It contains a double-bonded oxygen atom and an organyl group ( R−C=O ) or hydrogen in the case of formyl group ( H−C=O ).